典型环境内分泌干扰物的来源、环境分布和主要环境过程Sources,Distribution and Major Transformation Process of Typical Endocrine Disruptors in the Environment
杨清伟;梅晓杏;孙姣霞;胡莺;
摘要(Abstract):
内分泌干扰物(EDCs)作为一种新兴污染物,具有憎水性、低剂量效应和半衰期长等特征,在全球的土壤/沉积物中已被广泛检测到,并发现已给环境带来了严重的威胁。本文重点综合评述了近10年来土壤/沉积物中EDCs的来源、浓度水平、空间分布及吸附特性的研究。结果发现,EDCs来源涉及农业、工业和生活等多个方面;空间分布上,一般呈近海地区沉积物中EDCs浓度水平较河流底泥及土壤低,而高度工业化、城市化地区土壤/沉积物中EDCs浓度亦较高;EDCs的吸附受土壤/沉积物理化性质、EDCs自身性质和环境条件的共同影响,一般土壤有机质的含量和成熟度、土壤颗粒的比表面积与其吸附能力呈正相关,黏土矿物类型对EDCs的吸附也有重要的影响;EDCs的吸附能力与其自身的疏水性和结构特征有关;温度升高和溶液p H值增加都不利于EDCs的吸附,而溶液离子强度的增加对其吸附起着促进作用。土壤/沉积物对EDCs的吸附是一个复杂的过程,因此对其吸附特性需要进一步的探讨。
关键词(KeyWords): 内分泌干扰物;土壤或沉积物;环境分布;吸附特征
基金项目(Foundation): 国家自然科学基金(51508057;40871222);; 重庆交通大学内河航道整治技术交通行业重点实验室基金(NHHD-201516);重庆交通大学水利水运工程教育部重点实验室基金(SLK2017B04);; 重庆市基础与前沿研究计划重点(cstc2015jcyj BX0041)
作者(Author): 杨清伟;梅晓杏;孙姣霞;胡莺;
Email:
DOI:
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