上海某城市污水处理厂污水中药物类个人护理用品(PPCPs)的调查研究Investigative Screening of Pharmaceuticals in a Municipal Wastewater Treatment Plant in Shanghai
柯润辉;蒋愉林;黄清辉;陈玲;
摘要(Abstract):
通过两次采集上海某大型污水处理厂的水样,采用超高效液相色谱-串联质谱(UPLC-MS/MS)技术对水样中的94种典型药物和个人护理用品(PPCPs)进行分析,并初步分析了污水处理工艺对典型药物的处理效果。结果显示,该厂污水中有咖啡因、布洛芬、酮洛芬、双氯酚酸、氧氟沙星、睾酮、诺龙、磺胺吡啶、磺胺甲恶唑、甲砜霉素、氟甲砜霉素、氯贝酸、磺胺二甲基嘧啶、磺胺间甲氧嘧啶、氯霉素和诺龙等15种药物被检出和定量。初沉出水中药物总浓度为8 643~10 481 ng·L1,主要为咖啡因,出厂水中药物总浓度为1 005~1 076 ng·L1。其中,磺胺二甲基嘧啶、甲砜霉素和氟甲砜霉素在相关报道中较少进行检测或没有检出。磺胺二甲基嘧啶、磺胺间甲氧嘧啶、氯霉素和诺龙4种药物经生化反应池(A/A/O)和二沉池处理之后未检出。以A/A/O为核心技术的污水处理工艺对咖啡因、氯霉素、甲砜霉素和诺龙等药物处理效率较好(85%~99%),但对大部分药物处理效果并不显著。
关键词(KeyWords): 新兴污染物;药物;抗生素;污水处理
基金项目(Foundation): 国家自然科学基金青年科学基金项目(批准号21007093);; 中央高校科研基本业务费专项(0400219216)
作者(Author): 柯润辉;蒋愉林;黄清辉;陈玲;
Email:
DOI:
参考文献(References):
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