我国地表水中磷酸三苯酯的多层次生态风险评估A Tiered Ecological Risk Assessment of Triphenyl Phosphate in Chinese Surface Waters
罗莹;刘娜;徐建;胡秀峰;许宜平;金小伟;
摘要(Abstract):
磷酸三苯酯(triphenyl phosphate,TPP)在电缆材料、塑料制品中被大量使用,是地表水中检出频率最高的有机磷酸酯类阻燃剂之一,近年来受到广泛关注。本文通过文献检索TPP的地表水环境暴露浓度以及对水生生物的毒性效应浓度,利用风险商(hazard quotient,HQ)和概率生态风险评价法(probabilistic ecological risk assessments,PERA)对我国主要地表水中的TPP进行多层次生态风险评价。结果显示,TPP在我国地表水中的浓度为0.2~96.3 ng·L~(-1),以生存为测试终点的急性毒性数据推导出的预测无效应浓度(predicted no effect concentration,PNEC)为36.49μg·L~(-1),而以繁殖、发育和生长等为测试终点的慢性毒性数据推导出的PNEC值为1.30μg·L~(-1)。基于急、慢性毒性数据计算的风险商均小于0.1。我国地表水中TPP对0.1%到1%的水生生物造成繁殖、发育和生长等慢性毒性影响的概率分别为1.40%和0.04%,存在较低的潜在生态风险。
关键词(KeyWords): 磷酸三苯酯;物种敏感度分布曲线;生态风险评估;地表水
基金项目(Foundation): 国家水体污染控制与治理科技重大专项(2017ZX07302-001);; 国家自然科学基金(41673120);; 国家自然科学重点基金(21437006)
作者(Author): 罗莹;刘娜;徐建;胡秀峰;许宜平;金小伟;
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DOI:
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