赵洪霞;孙世宾;姜菁秋;王运涛;

• 1:大连理工大学环境学院工业生态和环境工程教育部重点实验室

摘要(Abstract)：

卤代苯酚(HPs)是一类广泛存在于水体中的污染物,其在污水处理厂出水中的存在及迁移转化会产生一定的健康和生态风险。探究卤代苯酚在环境中的转化行为非常重要。光降解反应是酚类物质在水体中迁移转化的重要途径,实际水体中的有机质等对卤代苯酚的光降解会产生一定的影响。对大连市区6家污水处理厂出水中卤代苯酚的污染状况进行了调查,结果显示在所有出水中总HPs的浓度范围为77.2~168.6 ng·L-1。在所有检出的卤代苯酚中,五氯酚和2,6-二氯酚浓度较高,且检出频率均为100%,检出浓度范围分别为10.8~166.7 ng·L-1和0.1~72.2 ng·L-1。在模拟太阳光照射条件下,选取2种氯酚和2种溴酚研究它们在污水样品与纯水中光降解行为,从卤原子取代的程度和种类两方面对不同卤代苯酚光降解的规律进行类比,分析了其光降解特性。此外,对比分析了不同污水厂出水的对同种卤代苯酚降解速率的影响,发现出水的p H值、溶解性有机质等因素,都可能影响卤代苯酚的光降解。

关键词(KeyWords)： 卤代苯酚;污水处理厂;出水;光降解

Abstract:

Keywords:

基金项目(Foundation): 国家自然科学基金(No.21677023);; 城市水资源与水环境国家重点实验室开放基金项目(哈尔滨工业大学,No.QAK201606)

作者(Author): 赵洪霞;孙世宾;姜菁秋;王运涛;

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